南阳凹陷原油含氮化合物组成及其控制因素     

李水福  何生  张冬梅 《地质科技情报》2006,25(5):52-56

原油的含氮化合物总量及其组成特征不仅受原油运移距离影响,而且还受成油母质类型和成熟度影响.对南阳凹陷27个原油含氮化合物的研究表明,其油气运移指向的规律性不强,原因主要是由于原油运移距离较短,地质色层效应不明显.魏岗南部和北部原油的成熟度差异较大,但含氮化合物组成特征总体上非常相似,表明南阳凹陷原油的含氮化合物总量及其组成主要受控于成油母质类型.  相似文献   

细菌反硝化法同时分析天然水中硝酸盐氮、氧同位素组成研究   总被引：6，自引：0，他引：6  

毛绪美  罗泽娇  刘存富  刘江霞  李永勇 《地质科技情报》2006,25(5):97-100

细菌反硝化法是目前同时分析天然水中硝酸盐氮、氧同位素组成的最新方法。该方法包括反硝化菌的选取与培养,利用反硝化菌将硝酸根完全转化成N2O气体以及N2O气体的提取、纯化和同位素测定。该方法采用硝酸盐标准,对测试结果需进行试剂本底、同位素分馏、同位素交换校正。与传统方法相比,细菌反硝化法可同时分析低浓度微量水中硝酸盐的氮、氧同位素组成,且速度更快捷,结果更可靠。  相似文献   

Carbon sources of fish in an Amazonian floodplain lake     

A. Cristina B. Oliveira  M. Gercilia M. Soares  L. Antonio. Martinelli  M. Zacarias. Moreira 《Aquatic Sciences - Research Across Boundaries》2006,68(2):229-238

  相似文献   

石家庄地面水回渗地下过程的氮行为影响试验研究   总被引：1，自引：0，他引：1  

张云  王秀艳  刘长礼  张明 《地球学报》2007,28(1):43-49

石家庄是我国北方地下水位下降较大的城市之一,利用其毗邻滹沱河宽阔河滩,地面水可直接入渗补给地下水的有利水文地质条件,实施地面水回渗地下工程,将具有现实意义.为探索地面水回渗后的水质变化,该文针对地面水在回渗过程中对水质起限制性影响的氮行为作用进行了模拟试验研究.结果显示,利用2 m厚的滹沱河细砂土及与粘土按一定比例的混合砂土层,可对间歇式实施地面水回渗中的铵氮组分形成一定容量的截留去除,并且该截留量又在随回渗次数的增加而缓慢下降,当采用人工增加环境碱度及湿度的办法后可消除这种下降.同时,还显示对回渗水中硝酸氮的去除率不高,但若采用人工添加乙醇碳源和接种优势脱氮微生物菌种方法,硝酸氮的去除率将会得到较大提高.  相似文献   

吉林省某锑矿分离砷的研究   总被引：1，自引：0，他引：1  

宋发兴  万飞  赵向前  刘晓菊 《吉林地质》2007,26(3):78-83

采用以水玻璃、硫酸为主的组合抑制剂,浮砷抑锑。较好地解决了砷锑分离的难题,使锑的精矿含砷降到符合国家质量标准。  相似文献   

半微量凯氏法测定土壤全氮量的不确定度评定   总被引：2，自引：2，他引：2  

白金峰  胡外英  张勤  周建辉 《岩矿测试》2007,26(1):40-44

以半微量凯氏法测定土壤中全氮量为例，对测定结果的不确定度来源进行了详细分析，对测定过程中的主要不确定度分量进行了合理评定，包括样品和标准物质硼砂的称量引入的不确定度，硼砂的纯度引入的不确定度，容量瓶、移液管和滴定管的体积引入的不确定度．相关元素的摩尔质量引入的不确定度以及测量的重复性引入的不确定度。最后合成标准不确定度．通过乘以95％置信概率下的扩展因子2获得测量结果的扩展不确定度。  相似文献   

多目标地球化学调查土壤样品中氮和碳的快速测定   总被引：2，自引：1，他引：2  

于兆水  胡外英张勤 《岩矿测试》2007,26(3):235-237

详细研究了元素分析仪的工作条件，建立了直接固体进样同时测定多目标地球化学调查土壤样苎支氮、碳的方法。方法简便、快速，检出限为氮14．5μg／g、碳0．013％。经土壤国家一级标准物质分析验证，测定值与标准值相符，精密度（RSD，n=12）为氮1．49％-3．27％、碳0.64％～3.63％。  相似文献   

The Atmospheric Oxidation of the HS Radical: Reaction with NO2     

Stella M. Resende 《Journal of Atmospheric Chemistry》2007,56(1):21-32

The atmospheric reaction between HS and NO₂ was theoretically investigated at 298 K and 1 atm of pressure. Our results show that the first reaction step will lead to the formation of HSNO₂ or HSONO, spontaneously and exothermically. HSONO easily decomposes into HSO + NO. On the other hand, HSNO₂ can hardly dissociate in the reactants, and its isomerization to other adducts is much hindered. Production of HNO + SO and SNO + OH was found to be unfavorable. Thus, the main products would be HSO + NO and HSNO₂, and new investigations focusing on the atmospheric fate of HSNO₂ are suggested. A general discussion of the fate of HS under atmospheric conditions is presented. Recent investigations indicate that NO₂, O₂ and N₂O should be the most important oxidants of HS, while the O₃ influence will not be significant.  相似文献   

Potential salinity limitations on nitrogen fixation in sediments from Mono Lake, California   总被引：2，自引：0，他引：2  

David B. Herbst 《International Journal of Salt Lake Research》1998,7(3):261-274

Mono Lake is a hypersaline alkaline lake in the high altitude Great Basin desert of eastern California. Algal productivity of the lake is nitrogen-limited, and a contributing source is derived from benthic nitrogen fixation. Lake level and salinity have fluctuated with natural climatic variations but have also been affected by the diversion of tributary streams. This research examines the influence of varied salinity and lake level on the potential for benthic nitrogen fixation in Mono Lake. A sediment-surface microbial mat community was exposed directly, and in acclimated cultures, to a range of Mono Lake salinities under anaerobic incubations and the activity of nitrogenase assayed by acetylene reduction. Activity was stimulated in light, but also occurred in darkness. Over an experimental salinity range from 50 to 150 g L⁻¹ TDS, nitrogenase activity was reduced by 90 per cent, with the activity persisting at the highest salinity being attributable to dark fixation alone. Between a salinity of 50 g L⁻¹, occurring in Mono Lake over 50 years ago, and 100 g L⁻¹, nitrogenase activity was reduced by nearly half. Changes in the area of the littoral zone at varied lake levels also affect the total amount of potential benthic nitrogen fixation in the lake. An accounting of yearly inputs of nitrogen to Mono Lake suggests N₂-fixation could contribute as much as 76–81 percent of the total. Inhibition of nitrogen fixation rates by increased salinity could limit the long-term nutrient supply and benthic primary productivity of this ecosystem.  相似文献   

Measurements of Reaction Coefficients of NO2 and HONO on Aerosol Particles     

Roy M. Harrison  Gareth M. Collins 《Journal of Atmospheric Chemistry》1998,30(3):397-406

The reaction coefficients of nitrogen dioxide and nitrous acid with monodisperse sodium chloride and ammonium sulphate aerosols have been measured in a flow reactor at atmospheric pressure. These experiments were performed at relative humidities above and below the deliquescence points of both aerosols (r.h. 50 and 85%) at 279 K. The results for NO₂ afford a reaction coefficient in the range (2.8–10) × 10^-4 and for HONO, (2.8–4.6) × 10^-3. For both species, there appears to be an enhancement of the reaction coefficient on sodium chloride aerosol at 50% r.h. The results are compared with reaction coefficients determined by other experimental methods. A good agreement is found for both gases between this method and the coated denuder method previously developed in our research laboratories (Msibi et al., 1993) and with the majority of other published data for NO₂. In the case of HONO, our estimate of reaction coefficient is smaller than, or at the lower limits of the ranges reported by other published studies.  相似文献